Cerofolini’s Model and the Fractal Adsorption Isotherms
نویسندگان
چکیده
The close link between the roughness of a surface and its adsorptive properties in Cerofolini’s model yields, with an adequate choice adsorption energy, well-known Dubinin-Radushkevich or Freundlich isotherms. Assuming fractal behavior concerning both energetic geometric heterogeneities described by power-law expressions dimensions, paper will develop some Using our theoretical approach, isotherms provide insights not only into geometry but also heterogeneities, implying that sorbent does need to be porous apply isotherm: on “flat” surfaces can dimensions related disorders. For example, theory applied computing nanoparticle catalysts, Rh/Al2O3, Rh/TiO2, Rh/WO3.
منابع مشابه
Water adsorption isotherms of lipids.
Hydration of bilayer lipids is a fundamental property of biological membranes. The available database of lipid hydration isotherms is fitted over the entire range of water activities by using a statistical mechanical approach that is an extension of the common Brunauer-Emmett-Teller model, to include differential energies of association for water molecules beyond the first strongly bound layer....
متن کاملOxide-dependent adsorption of a model membrane phospholipid, dipalmitoylphosphatidylcholine: bulk adsorption isotherms.
The importance of substrate chemistry and structure on supported phospholipid bilayer design and functionality is only recently being recognized. Our goal is to investigate systematically the substrate-dependence of phospholipid adsorption with an emphasis on oxide surface chemistry and to determine the dominant controlling forces. We obtained bulk adsorption isotherms at 55 degrees C for dipal...
متن کاملSimulated water adsorption isotherms in carbon nanopores
Water adsorption isotherms are calculated by grand canonical Monte Carlo simulations for the SPC/E water model in carbon nanopores at 298K. The pores are of slit or cylindrical morphology. Carbon-slit pores are of widths 0.8, 1.0 and 1.6 nm. The simulated single-walled carbon nanotubes are of 1.4 and 2.7 nm diameter ((10:10) and (20:20) respectively). In all cases considered, the adsorption iso...
متن کاملMoisture Diffusion in Cementitious Materials Adsorption Isotherms
This article describes an improvement on a previous model proposed by Ba~ant and Najjar, in which moisture diffusivity and moisture capacity are treated as separate parameters. These parameters are evaluated from independent test results, and are shown to depend on the water:cement ratio, curing time, temperature, and cement type. The moisture capacity is obtained as the slope of the adsorption...
متن کاملAdsorption Isotherms on Fluoride Removal: Batch Techniques
The ability of cynodon dactylon based thermally activated carbon to remove fluoride from aqueous solution has been investigated. The batch adsorption studies were carried out at neutral pH as the functions of contact time, adsorbent dose, adsorbate concentration, temperature and effect of co-anions, which are commonly present in water. The rate of adsorption was rapid during initial 105 minutes...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Fractal and fractional
سال: 2023
ISSN: ['2504-3110']
DOI: https://doi.org/10.3390/fractalfract7030262